Polymers Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA.
ACS Appl Mater Interfaces. 2009 Jul;1(7):1561-6. doi: 10.1021/am9002205.
Polymer colloids with an interfacial coating of purified single-wall carbon nanotubes (SWCNTs) are synthesized from length- and type-sorted SWCNTs. Aqueous nanotube suspensions sorted through density-gradient ultracentrifugation are used to emulsify spherical polymer colloids of microscale dimensions that are characterized through a combination of optical microscopy, transmission electron microscopy, and impedance spectroscopy. The SWCNT-polymer composite particles exhibit electrical conductivities comparable to or better than those of bulk SWCNT-polymer composites at nanotube loadings of more than 1 order of magnitude lower. The composite particles retain the unique electronic and optical characteristics of the parent SWCNT solution with potential applications as microelectronic and microoptical components.
具有纯化单壁碳纳米管(SWCNT)界面涂层的聚合物胶体是通过长度和类型排序的 SWCNT 合成的。通过密度梯度超速离心分离的水溶液纳米管悬浮液用于乳化微尺度的球形聚合物胶体,通过光学显微镜、透射电子显微镜和阻抗谱对其进行表征。在比多壁碳纳米管-聚合物复合材料低一个数量级以上的碳纳米管负载下,SWCNT-聚合物复合材料颗粒表现出与多壁碳纳米管-聚合物复合材料相当或更好的电导率。复合颗粒保留了原始 SWCNT 溶液的独特电子和光学特性,具有作为微电子和微光元件的潜在应用。