Department of Applied Physics, Royal Melbourne Institute of Technology, Melbourne, Victoria 3000, Australia.
Phys Rev Lett. 2009 Dec 18;103(25):258302. doi: 10.1103/PhysRevLett.103.258302. Epub 2009 Dec 17.
The current correlation function is determined from dynamic light scattering measurements of a suspension of particles with hard spherelike interactions. For suspensions in thermodynamic equilibrium we find scaling of the space and time variables of the current correlation function. This finding supports the notion that the movement of suspended particles can be described in terms of uncorrelated Brownian encounters. However, in the metastable fluid, at volume fractions above freezing, this scaling fails.
当前的相关函数是通过对具有硬球相互作用的粒子悬浮液的动态光散射测量来确定的。对于处于热力学平衡的悬浮液,我们发现电流相关函数的空间和时间变量的标度。这一发现支持了这样一种观点,即悬浮颗粒的运动可以用无关联的布朗遭遇来描述。然而,在亚稳流体中,在过冷的体积分数以上,这种标度失效了。