高效氧化的碳-碳偶联与 SBA-15 负载铁三联吡啶催化剂。
Highly efficient oxidative carbon-carbon coupling with SBA-15-support iron terpyridine catalyst.
机构信息
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
出版信息
Chem Commun (Camb). 2010 Apr 28;46(16):2739-41. doi: 10.1039/c001209b. Epub 2010 Mar 4.
DOI:10.1039/c001209b
PMID:20369167
Abstract
SBA-15-Fe(terpy)(2+) complex efficiently catalyzed oxidative C-C cross-coupling reactions of tertiary amines with carbon nucleophiles in high product yields. The supported terpyridine ligand can be recycled by filtration.
摘要
SBA-15-Fe(terpy)(2+) 配合物能高效催化叔胺与碳亲核试剂的氧化 C-C 交叉偶联反应，得到高产率的产物。负载的三联吡啶配体可通过过滤回收。
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