National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
ChemSusChem. 2010 May 25;3(5):541-9. doi: 10.1002/cssc.201000023.
There is a demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. Lithium and sodium borohydride, ammonia borane, hydrazine, and formic acid have been extensively investigated as promising hydrogen storage materials based on their relatively high hydrogen content. Significant advances, such as hydrogen generation temperatures and reaction kinetics, have been made in the catalytic hydrolysis of aqueous lithium and sodium borohydride and ammonia borane as well as in the catalytic decomposition of hydrous hydrazine and formic acid. In this Minireview we briefly survey the research progresses in catalytic hydrogen generation from these liquid-phase chemical hydrogen storage materials.
人们对充足且可持续的能源供应有需求。因此，由于氢能具有多种优点，寻找适用的储氢材料变得极其重要。基于其相对较高的含氢量，人们广泛研究了锂和硼氢化钠、氨硼烷、肼和甲酸作为有前途的储氢材料。在催化水解水溶液中的锂和硼氢化钠以及氨硼烷、水合肼和甲酸的催化分解方面，已经取得了重大进展，例如制氢温度和反应动力学。在这篇综述中，我们简要地综述了从这些液相化学储氢材料中催化制氢的研究进展。
