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ZIF-8 固载镍纳米粒子:高效催化剂用于氨硼烷水解制氢。

ZIF-8 immobilized nickel nanoparticles: highly effective catalysts for hydrogen generation from hydrolysis of ammonia borane.

机构信息

National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, Japan.

出版信息

Chem Commun (Camb). 2012 Mar 28;48(26):3173-5. doi: 10.1039/c2cc17302f. Epub 2012 Feb 20.

Abstract

Highly dispersed Ni nanoparticles have been successfully immobilized by the zeolitic metal-organic framework ZIF-8 via sequential deposition-reduction methods, which show high catalytic activity and long durability for hydrogen generation from hydrolysis of aqueous ammonia borane (NH(3)BH(3)) at room temperature.

摘要

高度分散的 Ni 纳米颗粒已成功通过顺序沉积-还原方法被沸石金属-有机骨架 ZIF-8 固定化,其在室温下水解氨硼烷(NH(3)BH(3))生成氢气具有高催化活性和长耐久性。

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