二聚天然产物根荚菌素 C9-C23（C9'-C23'）片段的合成。
Synthesis of the C9-C23 (C9'-C23') fragment of the dimeric natural product rhizopodin.
机构信息
Laboratory of Chemical Genomics, Peking University Shenzhen Graduate School, University Town of Shenzhen, Xili, Nanshan District, Shenzhen, China.
出版信息
Org Lett. 2010 May 7;12(9):2036-9. doi: 10.1021/ol100515m.
PMID:20380407
Abstract
A stereoselective assembly of the C9-C23 (C9'-C23') fragment of rhizopodin, a 38-membered bis-lactone natural product, has been developed. A highly efficient approach to this fragment assembles >50% of the carbon skeleton and the stereochemical elements present in the natural product.
摘要
已开发出一种具有立体选择性的 rhizopodin（一种 38 元双内酯天然产物的 C9-C23（C9'-C23'）片段）的组装方法。该片段的高效方法可组装出超过 50%的碳骨架和天然产物中存在的立体化学元素。
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