C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506-6045, USA.
J Phys Chem A. 2010 May 6;114(17):5462-7. doi: 10.1021/jp101193u.
Silica microspheres that are half-coated with platinum metal undergo self-propulsion in solutions of H(2)O(2), with the average speed increasing with increasing H(2)O(2) concentration. Microscopic observation of the particle motion, with segmentation of the image data, demonstrates that the particles move, on average, with the platinum-coated region oriented opposite to the direction of motion. Velocity autocorrelation and motion direction analyses show that the direction of motion is highly correlated with the particle orientation. The effect of the observation time interval on the measured translational diffusion coefficient and the apparent particle motion is analyzed.
经半包裹铂金属的二氧化硅微球在 H(2)O(2)溶液中会发生自推进,随着 H(2)O(2)浓度的增加,平均速度也会增加。通过对粒子运动的微观观察,对图像数据进行分段,证明粒子平均以铂涂层区域朝向运动方向相反的方向移动。速度自相关和运动方向分析表明,运动方向与粒子方向高度相关。分析了观测时间间隔对测量的平移扩散系数和粒子表观运动的影响。