Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand.
Dalton Trans. 2010 May 7;39(17):4032-4. doi: 10.1039/c002885c. Epub 2010 Mar 16.
The reaction of PhBCl(2) with free base triarylcorroles results in a spontaneous reduction to give diboron corrole complexes (PhBHBPh)(Cor) in which a proton has been captured to form a bridging B-H-B group encapsulated within the corrole ligand. The proposed mechanism is supported by the reaction of PhBF(2) with H(3)Cor to give (PhBF)(BPh)(Cor) in which no reduction has occurred.
PhBCl(2)与游离三芳基卟啉反应自发还原生成二硼卟啉配合物(PhBHBPh)(Cor)，其中质子被捕获形成桥联 B-H-B 基团，被卟啉配体包裹。PhBF(2)与 H(3)Cor 反应生成(PhBF)(BPh)(Cor)，其中未发生还原反应，这一反应提出的机理得到了支持。
