Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588-0304, USA.
Angew Chem Int Ed Engl. 2010 Jun 1;49(24):4079-83. doi: 10.1002/anie.201000695.
is provided by the cyclophane substituent on iodine(III). Computational and experimental studies demonstrate that out of plane steric bulk strongly destabilizes the reductive elimination transition state, and leads to regiochemical control. This approach should be general for high valent main group and transition metal ions.
碘（III）上的环戊二烯基取代基提供了这种稳定性。计算和实验研究表明，面外的庞大基团强烈地使还原消除过渡态不稳定，并导致区域化学控制。这种方法应该适用于高价主族和过渡金属离子。
