Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstraße 15, 76131 Karlsruhe, Germany.
Chem Commun (Camb). 2011 Jan 7;47(1):221-3. doi: 10.1039/c002435j. Epub 2010 Apr 28.
We report on the utility of multifunctional, κ(1)Si:κ(3)S-coordinated tris(methimazolyl)silanide ligands Si(mt(Me))(3) for the stabilisation of a triangulo palladium cluster [Pd(3){Si(mt(Me))(3)}(2)] (3) consisting of very unusual μ(3)-capping SiR(3) donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
我们报告了多功能的 κ(1)Si:κ(3)S 配位三（甲巯基）硅烷配体Si(mt(Me))(3)用于稳定由非常不寻常的 μ(3)-封端 SiR(3)给体组成的三角钯簇[Pd(3){Si(mt(Me))(3)}(2)] (3)的用途。NMR 光谱和 DFT 计算支持了与相应的铂化学的差异。
