Department for the Modeling of Physico-Chemical Processes, Maria Curie-Skłodowska University, 20-031 Lublin, Poland.
J Chem Phys. 2010 Apr 28;132(16):164702. doi: 10.1063/1.3392744.
We report the phase diagrams for a square-shoulder, square-well fluids in two dimensions (2D), as well as confined in slitlike pores. The diagrams are obtained by histogram reweighting Monte Carlo simulations. The critical points are located by using finite size scaling analysis. Our calculations indicate that the phase behavior of the systems investigated is distinct from that observed in three dimensions. In particular, we have not found the liquid-liquid transition that occurs in the bulk.
我们报告了二维方形肩、方形阱流体以及受限在狭缝孔中的相图。这些相图是通过直方图再加权蒙特卡罗模拟得到的。临界点是通过有限尺寸标度分析确定的。我们的计算表明,所研究系统的相行为与在三维中观察到的不同。特别是,我们没有发现发生在本体中的液-液相变。