Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018WV, Amsterdam, The Netherlands.
Dalton Trans. 2010 Jun 21;39(23):5432-5. doi: 10.1039/c003352a. Epub 2010 May 5.
New coordination polymers based on different combinations of silver atoms and pyridyl-substituted N-heterocyclic carbene moieties are described. The addition of Zn(ii) templates leads to Ag-Zn supramolecular assemblies via selective ZnN interactions; a process that can be reverted.
介绍了几种基于不同组合的银原子和吡啶取代的 N-杂环卡宾部分的新型配位聚合物。添加 Zn(ii) 模板可以通过选择性的 ZnN 相互作用导致 Ag-Zn 超分子组装;这个过程是可逆的。