通过 AlCl3 催化的 [3+2] 环加成反应全合成 (+)-virgatusin。
Total synthesis of (+)-virgatusin via AlCl3-catalyzed [3+2] cycloaddition.
机构信息
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27500-3290, USA.
出版信息
Chem Commun (Camb). 2009 Sep 14(34):5135-7. doi: 10.1039/b911765b. Epub 2009 Jul 27.
DOI:10.1039/b911765b
PMID:20448971
Abstract
The AlCl(3)-catalyzed cycloaddition of a donor-acceptor (don-acc) cyclopropane and piperonal succinctly provides the core of virgatusin in a selective, high-yielding manner.
摘要
三氯化铝催化给体-受体（don-acc）环丙烷与胡椒醛的环加成反应以选择性和高产率简洁地提供了 Virgatusin 的核心结构。
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