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多酸负载钯纳米粒子作为高效催化剂,在无酸或卤素促进剂存在的条件下直接合成过氧化氢。

Polyoxometalate-supported Pd nanoparticles as efficient catalysts for the direct synthesis of hydrogen peroxide in the absence of acid or halide promoters.

机构信息

State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

Chem Commun (Camb). 2009 Sep 14(34):5174-6. doi: 10.1039/b910317a. Epub 2009 Jul 21.

Abstract

A Keggin-type polyoxometalate (Cs(1.5)H(1.5)PW(12)O(40))-supported Pd catalyst is efficient for the direct synthesis of H(2)O(2) from H(2) and O(2) in the absence of any acid or halide additives under atmospheric pressure.

摘要

一种 Keggin 型多金属氧酸盐(Cs(1.5)H(1.5)PW(12)O(40))负载的钯催化剂在无任何酸或卤素添加剂、常压下,能高效地将 H(2)和 O(2)直接合成 H(2)O(2)。

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