聚硅烷负载的钯和铂纳米颗粒作为有机合成的高效催化剂。
Polysilane-supported Pd and Pt nanoparticles as efficient catalysts for organic synthesis.
作者信息
Oyamada Hidekazu, Akiyama Ryo, Hagio Hiroyuki, Naito Takeshi, Kobayashi Shū
机构信息
Science of Process Laboratories, The HFRE Division, ERATO, Japan Science and Technology Agency (JST), Matoba, Kawagoe, Saitama 350-1101, Japan.
出版信息
Chem Commun (Camb). 2006 Nov 4(41):4297-9. doi: 10.1039/b610241g. Epub 2006 Sep 5.
DOI:10.1039/b610241g
PMID:17047846
Abstract
Polysilane-supported Pd and Pt catalysts have been prepared for the first time, and used successfully in hydrogenation, Suzuki and Sonogashira reactions, and hydrosilylation respectively: the reactions proceeded in high yields, and the catalysts could be recovered almost quantitatively by simple filtration and reused.
摘要
首次制备了聚硅烷负载的钯和铂催化剂，并分别成功应用于氢化反应、铃木反应和 Sonogashira 反应以及硅氢化反应：反应产率高，通过简单过滤几乎可以定量回收催化剂并重复使用。
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