Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Specially Functional Materials, South China University of Technology, 381 Wushan Road, Guangzhou 510640, People's Republic of China.
Chem Soc Rev. 2009 Dec;38(12):3391-400. doi: 10.1039/b816352a. Epub 2009 Jul 22.
Within organic optoelectronics, polymer light-emitting devices (PLEDs) are regarded as an important class of devices which can convert electricity into light as a result of radiative decay taking place in semiconducting polymers. Recently, much effort has been devoted to developing efficient white emitting PLEDs for their potential applications in next-generation flat-panel displays and solid-state lighting sources. In this tutorial review, we will summarize the advances in white emitting polymers and devices published up till April 2009 by major prestigious institutions in this field. Special attention is paid to the recent progress in highly efficient devices realized by doping an electrophosphorescent guest into a polymer host and other approaches. Also we will summarize the new strategies to realize white emission with simultaneous fluorescent and/or phosphorescent emission from a single polymer in which singlet and/or triplet chromophores are incorporated into the polymer side or main chain through a covalent bond.
在有机光电子学中,聚合物发光二极管(PLED)被视为一类重要的器件,它可以将电能转化为光,这是由于半导体聚合物中发生的辐射衰减。最近,人们致力于开发高效的白色发光 PLED,因为它们有可能应用于下一代平板显示器和固态照明光源。在本综述教程中,我们将总结截至 2009 年 4 月,该领域主要知名机构在白色发光聚合物和器件方面的进展。特别关注通过掺杂电磷光客体到聚合物主体中来实现高效器件的最新进展,以及其他方法。我们还将总结通过将单重态和/或三重态发色团通过共价键结合到聚合物侧链或主链中来实现白色发射的新策略,其中单重态和/或三重态发色团同时从单个聚合物中发出荧光和/或磷光。