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石墨烯和移动离子:全塑料、溶液处理发光器件的关键。

Graphene and mobile ions: the key to all-plastic, solution-processed light-emitting devices.

机构信息

Department of Physics, Umeå University, SE-90187 Umeå, Sweden.

出版信息

ACS Nano. 2010 Feb 23;4(2):637-42. doi: 10.1021/nn9018569.

Abstract

The emerging field of "organic" or "plastic" electronics has brought low-voltage, ultrathin, and energy-efficient lighting and displays to market as organic light-emitting diode (OLED) televisions and displays in cameras and mobile phones. Despite using carbon-based materials as the light-emitting layer, previous efficient organic electronic light-emitting devices have required at least one metal electrode. Here, we utilize chemically derived graphene for the transparent cathode in an all-plastic sandwich-structure device, similar to an OLED, called a light-emitting electrochemical cell (LEC). Using a screen-printable conducting polymer as a partially transparent anode and a micrometer-thick active layer solution-deposited from a blend of a light-emitting polymer and a polymer electrolyte, we demonstrate a light-emitting device based solely on solution-processable carbon-based materials. Our results demonstrate that low-voltage, inexpensive, and efficient light-emitting devices can be made without using metals. In other words, electronics can truly be "organic".

摘要

新兴的“有机”或“塑料”电子领域已经将低压、超薄和节能的照明和显示技术推向市场,例如有机发光二极管(OLED)电视和相机、手机中的显示屏。尽管使用基于碳的材料作为发光层,但以前高效的有机电子发光器件至少需要一个金属电极。在这里,我们在类似于有机发光二极管(OLED)的三明治结构全塑料器件中利用化学衍生的石墨烯作为透明阴极,称为发光电化学池(LEC)。使用可丝网印刷的导电聚合物作为部分透明的阳极和从发光聚合物和聚合物电解质的混合物溶液沉积的几微米厚的有源层溶液,我们展示了一种仅基于溶液可加工的基于碳的材料的发光器件。我们的结果表明,可以在不使用金属的情况下制造低压、廉价且高效的发光器件。换句话说,电子真的可以“有机”。

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