Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju, 660-701, S. Korea.
Dalton Trans. 2009 Aug 21(31):6096-8. doi: 10.1039/b906474e. Epub 2009 Jun 19.
The effect of varying donor X in otherwise structurally similar O(2)S(2)X-macrocycles (L(1): X = S, L(2): X = O and L(3): X = NH) on the corresponding assembly reactions with Cu(I) halides has been demonstrated to yield three supramolecular complexes with different architectures: L(1) resulted in a discrete dimeric complex (1), while L(2) and L(3) gave respectively 1D (2) and 2D (3) coordination polymers; the solid state photoluminescence of 3 is also described.
在结构相似的 O(2)S(2)X-大环（L(1)：X = S，L(2)：X = O 和 L(3)：X = NH）中，改变供体 X 的影响，已被证明会对与 Cu(I)卤化物的相应组装反应产生影响，生成具有不同结构的三种超分子配合物：L(1)生成离散的二聚体配合物（1），而 L(2)和 L(3)则分别生成 1D（2）和 2D（3）配位聚合物；还描述了 3 的固态光致发光。
