Laboratoire de Chimie de Coordination, Institut de Chimie, UMR 7177 CNRS, Université de Strasbourg, 4 rue Blaise Pascal, F-67070, Strasbourg Cedex, France.
Dalton Trans. 2009 Sep 21(35):7288-93. doi: 10.1039/b911439d. Epub 2009 Aug 4.
A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag(2)I(2) faces.
合成了一种新型杂双膦亚胺盐,并与 Ag(I) 反应,得到了一种不寻常的四银立方烷型簇合物,其中两个 P-NHC 配体在相反的 Ag(2)I(2) 面的 Ag(I) 中心之间桥接。