利用手性 DMAP 催化剂，MgI2 促进的环戊烯酮的对映选择性 Morita-Baylis-Hillman 反应。
MgI2-accelerated enantioselective Morita-Baylis-Hillman reactions of cyclopentenone utilizing a chiral DMAP catalyst.
机构信息
Department of Chemistry, Texas A&M University, PO Box 30012, College Station, TX 77842-3012, USA.
出版信息
Chem Commun (Camb). 2010 Apr 21;46(15):2644-6. doi: 10.1039/c001977a. Epub 2010 Mar 12.
DOI:10.1039/c001977a
PMID:20449328
Abstract
Fu's planar chiral DMAP catalyst efficiently promotes the asymmetric Morita-Baylis-Hillman reactions of cyclopentenone with a variety of aldehydes in the presence of MgI(2) as a cocatalyst.
摘要
傅里叶手性 DMAP 催化剂在 MgI(2)作为共催化剂的存在下，有效地促进了环戊烯酮与各种醛的不对称 Morita-Baylis-Hillman 反应。
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