在甲醇中，在中等温度下，酸催化纤维素直接转化为甲基葡萄糖苷。
Acid-catalysed direct transformation of cellulose into methyl glucosides in methanol at moderate temperatures.
机构信息
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
出版信息
Chem Commun (Camb). 2010 Apr 21;46(15):2668-70. doi: 10.1039/b925723c. Epub 2010 Feb 6.
DOI:10.1039/b925723c
PMID:20449333
Abstract
Cellulose can be transformed into methyl glucosides in methanol with yields of 50-60% in the presence of several acid catalysts under mild conditions (< or = 473 K); H(3)PW(12)O(40) provides the highest turnover number (approximately 73 in 0.5 h) for the formation of methyl glucosides among many acid catalysts examined.
摘要
纤维素在甲醇中可以在温和条件下（<或=473 K）在几种酸催化剂的存在下转化为甲基葡萄糖苷，产率为 50-60%；在许多所考察的酸催化剂中，H(3)PW(12)O(40)为甲基葡萄糖苷的形成提供了最高的周转数（在 0.5 h 内约为 73）。
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