[三价钌（edta）（H(2)O)（-）]介导的过氧化氢与羟基脲的氧化反应。动力学和机理研究。
[Ru(III)(edta)(H(2)O)](-) mediated oxidation of hydroxyurea with H(2)O(2). Kinetic and mechanistic investigation.
机构信息
Chemistry Group, Central Mechanical Engineering Research Institute, MG Avenue, Durgapur-713209, India.
出版信息
Dalton Trans. 2010 Feb 21;39(7):1695-8. doi: 10.1039/b920839a. Epub 2009 Dec 15.
DOI:10.1039/b920839a
PMID:20449405
Abstract
Reported in this paper is the first example of a ruthenium complex, Ru(III)(edta)(H(2)O) (edta = ethylenediaminetetra-acetate), that catalyzes the oxidation of hydroxyurea in the presence of H(2)O(2), mimicking the action of peroxidase or catalase and shedding light on their possible mechanism of action.
摘要
本文报道了首例钌配合物Ru(III)(edta)(H(2)O)（edta = 乙二胺四乙酸），该配合物在 H(2)O(2)存在下能够催化羟脲的氧化，模拟过氧化物酶或过氧化氢酶的作用，为其可能的作用机制提供了线索。
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