Department of Physics, Arts and Science Faculty, Inonu University, Malatya 44069, Turkey.
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Sep 1;76(5):435-8. doi: 10.1016/j.saa.2009.10.043. Epub 2009 Oct 31.
New Hofmann-T(d)- type complexes in the form of Ni(CyHEA)(2)M(CN)(4) (where CyHEA=2-(1-cyclohexenyl)ethylamine and M=Cd or Hg) have been prepared in powder form and their infrared (4000-100cm(-1)) and Raman (2800-1650cm(-1)) spectra have been reported. The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to the Hofmann-T(d)-type complexes.
已制备出 Ni(CyHEA)(2)M(CN)(4)(其中 CyHEA=2-(1-环己烯基)乙基胺,M=Cd 或 Hg)的新型霍夫曼-T(d)-型配合物,以粉末形式存在,并报告了其红外(4000-100cm(-1)) 和拉曼(2800-1650cm(-1))光谱。通过差示热分析(DTA)和热重分析(TGA)研究了这些配合物的热行为。结果表明,这些化合物在结构上与霍夫曼-T(d)-型配合物相似。