Department of Physics, Arts and Science Faculty, Inonu University, Malatya 44069, Turkey.
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Jul;79(2):308-11. doi: 10.1016/j.saa.2010.12.044. Epub 2010 Dec 22.
New Hofmann type benzene clathrates in the form of M(CyHEA)2Ni(CN)4·2benzene (where CyHEA=2-(1-cyclohexenyl)ethylamine and M=Ni or Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The results suggest that title compounds are similar in structure to Hofmann type clathrates and their structures consist of polymeric layers of |M-Ni(CN)4|∞ with the CyHEA molecule bounded to the metal atoms (M).
以粉末形式制备了形式为 M(CyHEA)2Ni(CN)4·2benzene 的新型霍夫曼型苯笼合物（其中 CyHEA=2-(1-环己烯基)乙胺，M=Ni 或 Cd），并报道了其傅里叶变换红外和拉曼光谱。结果表明，标题化合物在结构上与霍夫曼型笼合物相似，其结构由|M-Ni(CN)4|∞的聚合层组成，CyHEA 分子与金属原子（M）结合。
