State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China.
Chem Commun (Camb). 2010 Jul 7;46(25):4469-71. doi: 10.1039/c002870c. Epub 2010 May 12.
The first rare earth metal terminal imido complex has been isolated and structurally characterized. The complex has an extremely short M-N bond length and a nearly linear M-N-C angle. DFT studies showed two p orbitals of N(imido) atom form two bonds with two d orbitals of rare earth metal ion.
首例稀土金属末端亚氨基配合物被分离并进行了结构表征。该配合物具有极短的 M-N 键长和近乎线性的 M-N-C 键角。DFT 研究表明，N(亚氨基)原子的两个 p 轨道与稀土金属离子的两个 d 轨道形成两个键。
