Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, People's Republic of China.
Inorg Chem. 2010 Jun 21;49(12):5362-4. doi: 10.1021/ic1006555.
A mixed aluminum-sodium phenolate ring compound with an oxo core has been synthesized and crystallographically characterized as a new inverse crown ether complex, together with some of its precursors. The experimental results showed that the Al-Na inverse crown ether can be obtained from two different approaches: (1) hydrolysis of [(EDBP)Al(CH(3))(2)Na(THF)(2)] (1), followed by condensation with [(EDBP)Al(CH(3))(mu(2)-OH)Na(THF)(3)] (2); (2) fast redox reaction by oxidation of a methyl group on complex 1 and reduction of molecular oxygen to oxide.
已合成并晶体学表征了一种具有氧核的混合铝-钠苯并酚环化合物，作为一种新的反冠醚配合物，以及其部分前体。实验结果表明，Al-Na 反冠醚可以通过两种不同的方法获得：（1）[(EDBP)Al(CH(3))(2)Na(THF)(2)]（1）的水解，然后与[(EDBP)Al(CH(3))(mu(2)-OH)Na(THF)(3)]（2）缩合；（2）通过氧化 1 上的一个甲基和还原分子氧生成氧化物的快速氧化还原反应。
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