链状聚[[双（二甲基铵）[镉（II）-双（μ-1,1':4',1''-三联苯-3,3''-二羧酸根）]]二甲基甲酰胺溶剂化物]
catena-Poly[[bis-(dimethyl-ammonium) [cadmate(II)-bis-(μ-1,1':4',1''-terphenyl-3,3''-dicarboxyl-ato)]] dimethyl-formamide disolvate].
作者信息
Park Sang-Wook, Gu Ja-Min, Kim Youngmee, Huh Seong
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m71. doi: 10.1107/S1600536810051366.
In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10].
在标题化合物{(C₂H₈N)₂[Cd(C₂₀H₁₂O₄)₂]·2C₃H₇NO}ₙ中，镉(II)离子位于一个二重旋转轴上，处于扭曲的八面体CdO₆环境中，该环境由两个μ₂配位的1,1':4',1''-三联苯-3,3''-二羧酸酯（DCT）配体的四个O原子和两个μ₁配位的DCT配体的两个O原子定义。两种类型的DCT配体均起桥连作用，形成了一个平行于[10]延伸的一维聚合结构。
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