Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada.
Inorg Chem. 2013 Feb 18;52(4):1673-5. doi: 10.1021/ic3020223. Epub 2013 Feb 4.
A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a Zn(II)B-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N(2), argon, and CO(2).
一种带有三个羧基的发光三芳基硼配体已经被合成并进行了全面的表征。通过合成和分离出一种锌(II)硼金属有机骨架化合物（B-MOF-1），证明了其在含硼金属有机骨架（B-MOFs）中的应用。B-MOF-1 的晶体属于立方空间群 F432，具有 8 重穿插的网络和 ∼21%的空隙。B-MOF-1 表现出蓝色荧光，并且能够适度地吸附氮气、氩气和二氧化碳等气体。
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