Matsubara K, Kawata S, Minami S
Appl Opt. 1988 Mar 15;27(6):1160-3. doi: 10.1364/AO.27.001160.
A new optical chemical sensor was developed for chemical sensing based on light-excited surface plasmon measurement. Concentration of the chemical species is found in liquid or gas without the help of a reagent but by measuring the resonance condition of the surface plasmon on the sensing metal surface. The resonance condition is given by the dielectric constant of the sample faced on the metal. The developed sensor can be compact and simple, because of the absence of mechanical moving parts, by using multichannel angular light intensity detection with a photodiode array and a Fourier transform optical setup. Experimental results are shown for measurement of ethanol concentration in water. The detection limit for ethanol in water was 10(-4) wt./wt. by the experiments with the developed system.
基于光激发表面等离子体测量开发了一种用于化学传感的新型光学化学传感器。无需试剂,而是通过测量传感金属表面上表面等离子体的共振条件,来测定液体或气体中化学物质的浓度。共振条件由与金属表面接触的样品的介电常数决定。由于没有机械运动部件,通过使用光电二极管阵列进行多通道角光强检测和傅里叶变换光学装置,所开发的传感器可以做到紧凑且简单。给出了用于测量水中乙醇浓度的实验结果。通过所开发系统进行的实验,水中乙醇的检测限为10(-4) wt./wt.