一种基于肟的新型六核锰(III)单分子磁体，具有高各向异性能量势垒。
A new family of oxime-based hexanuclear manganese(III) single molecule magnets with high anisotropy energy barriers.
机构信息
Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Case courrier 42, Université Pierre et Marie Curie Paris 6, Place Jussieu, 75252 Paris Cedex 05, France.
出版信息
Chem Commun (Camb). 2010 Jul 28;46(28):5106-8. doi: 10.1039/c0cc00485e. Epub 2010 Jun 7.
PMID:20532259
Abstract
A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state.
摘要
对两种水杨醛亚胺基肟基构筑的{Mn(6)}单分子磁体的磁结构研究表明，其各向异性能量势垒可与当前 d 过渡金属配合物的纪录相媲美，强烈依赖于配体的精确排列和溶剂化状态。
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