Department of Chemistry and Biochemistry, University of Texas - Arlington, Arlington, Texas 76019, USA.
Phys Chem Chem Phys. 2010 Jul 21;12(27):7688-94. doi: 10.1039/b922123a. Epub 2010 Jun 8.
A novel, self-consistent, algebraic method is developed within the framework of Maxwell-Wagner theory (i.e., 'mixture formula' and single shell model) for obtaining the dielectric parameters, such as epsilon(s), kappa(s) and f(Q) of spherical shells. The efficacy of the procedure that-in contrast to previous ones-is void of any approximations, was successfully tested by reanalyzing existing data on polystyrene microcapsules.
本文在 Maxwell-Wagner 理论(即“混合公式”和单壳模型)的框架内,开发了一种新颖的、自洽的代数方法,用于获得球形壳的介电参数,如 epsilon(s)、kappa(s) 和 f(Q)。与之前的方法不同,该方法没有任何近似,通过重新分析现有关于聚苯乙烯微胶囊的数据,成功验证了该程序的有效性。