钌催化串联烯炔复分解/氢甲酰化反应。
Ruthenium-catalyzed tandem enyne metathesis/hydrovinylation.
机构信息
Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.
出版信息
Chem Commun (Camb). 2010 Aug 21;46(31):5692-4. doi: 10.1039/c0cc00008f. Epub 2010 Jun 24.
PMID:20577666
Abstract
In situ modification of Grubbs' first-generation metathesis catalyst allows for a tandem enyne metathesis/hydrovinylation that is complementary to the regioselectivity of known ruthenium-catalyzed hydrovinylations.
摘要
原位修饰 Grubbs 第一代复分解催化剂可以实现串联烯炔复分解/氢甲酰化反应，这与已知的钌催化氢甲酰化反应的区域选择性互补。
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