Rumpf K, Granitzer P, Poelt P
Nanoscale Res Lett. 2009 Nov 15;5(2):379-82. doi: 10.1007/s11671-009-9492-6.
A magnetic semiconductor/metal nanocomposite with a nanostructured silicon wafer as base material and incorporated metallic nanostructures (Ni, Co, NiCo) is fabricated in two electrochemical steps. First, the silicon template is anodized in an HF-electrolyte to obtain a porous structure with oriented pores grown perpendicular to the surface. This etching procedure is carried out either in forming a sample with a single porous layer on one side or in producing a double-sided specimen with a porous layer on each side. Second, this matrix is used for deposition of transition metals as Ni, Co or an alloy of these. The achieved hybrid material with incorporated Ni- and Co-nanostructures within one sample is investigated magnetically. The obtained results are compared with the ones gained from samples containing a single metal.
一种以纳米结构硅片为基材并结合金属纳米结构(镍、钴、镍钴合金)的磁性半导体/金属纳米复合材料,通过两步电化学方法制备而成。首先,将硅模板在氢氟酸电解液中进行阳极氧化,以获得具有垂直于表面生长的定向孔的多孔结构。此蚀刻过程既可以通过在一侧形成具有单个多孔层的样品来进行,也可以通过制备两侧均带有多孔层的双面样品来实现。其次,该基体用于沉积镍、钴等过渡金属或它们的合金。对在一个样品中结合了镍和钴纳米结构的所得混合材料进行磁性研究。将所得结果与从含有单一金属的样品中获得的结果进行比较。