Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400, USA.
Org Lett. 2010 Sep 3;12(17):3729-31. doi: 10.1021/ol101432m.
Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.
(H(2)IMes)Cl(2)Ru=CHPh(OiPr)与交替 ROMP 的催化作用,第二代 Hoveyda-Grubbs 催化剂,提供了完全的环状交替聚合物。循环 AROMP 的条件用于制备其中一个重复单元带有伯烷基氯的聚合物,该氯可用于进一步的修饰。