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利用高灵敏度气体传感器对持久性有机污染物进行新型简便检测。

Novel facile detection of persistent organic pollutants using highly sensitive gas sensor.

机构信息

The Key Laboratory of Biomimetic Sensing and Advanced Robot Technology, Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, PR China.

出版信息

Talanta. 2010 Jun 30;82(1):409-16. doi: 10.1016/j.talanta.2010.04.007. Epub 2010 Apr 13.

Abstract

Persistent organic pollutants (POPs) are greatly noxious chemicals in environment, and they can cumulate in organisms and transfer between different species. Therefore, it is significant to detect POPs for both environmental evaluation and further treatment. However, developing facile approach for the detection of POPs still remains a challenge so far. In this paper, we report an innovative method for facile detection of POPs using gas sensor for the first time. Porous SnO(2) nanostructures with a special tri-walled structure prepared via hydrothermal route and annealing process, were employed as gas-sensing materials. Through gas measurements, it was revealed that the as-fabricated gas sensor exhibited highly sensitive performance towards target POPs, including methoxychlor, mirex, p,p'-DDT, and aldrin. Moreover, we found that target POPs were distinguishable by extracting characteristics in kinetic curves of gas adsorption-desorption. As the presented detecting approach is facile without the requirements of complex operations, expensive and bulky instruments, it is expected that it would be developed as a promising method for the detection of POPs, and thereby showing its significance for environmental monitoring.

摘要

持久性有机污染物(POPs)是环境中危害极大的化学物质,它们可以在生物体内积累,并在不同物种之间转移。因此,检测 POPs 对于环境评估和进一步处理都具有重要意义。然而,开发简便的 POPs 检测方法至今仍是一个挑战。本文首次报道了一种利用气体传感器简便检测 POPs 的新方法。通过水热法和退火工艺制备了具有特殊三壁结构的多孔 SnO2 纳米结构,用作气体传感材料。通过气体测量,结果表明所制备的气体传感器对目标 POPs(包括甲氧氯、灭蚁灵、p,p'-DDT 和艾氏剂)表现出高度敏感的性能。此外,我们发现通过提取气体吸附-解吸动力学曲线中的特征,可以区分目标 POPs。由于所提出的检测方法简便,不需要复杂的操作、昂贵和庞大的仪器,因此有望开发成为一种有前途的 POPs 检测方法,从而显示其在环境监测方面的重要意义。

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