金（I）催化的丙二烯水合反应
Gold(I)-Catalyzed Hydration of Allenes.
作者信息
Zhang Zhibin, Du Lee Seong, Fisher Aaron S, Widenhoefer Ross A
机构信息
Department of Chemistry, Duke University, French Family Science Center, Durham, NC 27708-0346, USA.
出版信息
Tetrahedron. 2009 Feb 28;65(9):1794-1798. doi: 10.1016/j.tet.2008.10.113.
Abstract
A gold(I) N-heterocyclic carbene complex catalyzes the intermolecular hydration of allenes to form allylic alcohols in modest yield with selective delivery of water to the terminal carbon atoms of the allenyl moiety.
摘要
一种金（I）氮杂环卡宾配合物催化丙二烯的分子间水合反应，以适度的产率生成烯丙醇，并将水选择性地输送到丙二烯部分的末端碳原子上。
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