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一种新型大环双核铜(II)配合物的阴离子识别和传感：碘化物的选择性受体。

Anion recognition and sensing by a new macrocyclic dinuclear copper(II) complex: a selective receptor for iodide.

机构信息

Department of Chemistry, Jackson State University, Jackson, Mississippi 39212, USA.

出版信息

Inorg Chem. 2010 Aug 16;49(16):7223-5. doi: 10.1021/ic100686m.

DOI:10.1021/ic100686m
PMID:20690729
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2919498/
Abstract

A macrocyclic dinuclear copper complex, [Cu(2)(II)(1)Br(3)(H(2)O)]Br, has been synthesized and characterized by X-ray crystallography, in which the macrocycle is folded to form a bowl-shaped cavity. The sensing ability of the receptor has been studied for halides by UV-vis spectroscopy in water-acetonitrile (1:3, v/v) and water. The results indicate that the new receptor exhibits a strong affinity and selectivity for iodide.

摘要

一种大环双核铜配合物，[Cu(2)(II)(1)Br(3)(H(2)O)]Br，已经通过 X 射线晶体学合成和表征，其中大环折叠形成碗状空腔。通过在水-乙腈（1:3，v/v）和水中的紫外可见光谱研究了受体对卤素的传感能力。结果表明，新型受体对碘化物表现出很强的亲和力和选择性。

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