Tomat Elisa, Cuesta Luciano, Lynch Vincent M, Sessler Jonathan L
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA.
Inorg Chem. 2007 Aug 6;46(16):6224-6. doi: 10.1021/ic700933p. Epub 2007 Jul 14.
Reactions of the Schiff base oligopyrrolic octaazamacrocycle 1 with BF4- salts of divalent zinc and cadmium result in fluoride anion abstraction and the formation of difluoride-bridged metal complexes. X-ray diffraction analyses provide support for the notion that hydrogen-bonding interactions, involving the N-H groups of the macrocycle and the coordinated fluoride ions, play an important role in stabilizing these new complexes.
席夫碱寡聚吡咯八氮大环化合物1与二价锌和镉的四氟硼酸盐反应会导致氟阴离子的离去，并形成二氟桥连的金属配合物。X射线衍射分析支持了这样一种观点，即涉及大环的N-H基团和配位氟离子的氢键相互作用在稳定这些新配合物中起着重要作用。
