Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Chem Commun (Camb). 2010 Sep 21;46(35):6515-7. doi: 10.1039/c0cc01141j. Epub 2010 Aug 10.
Solid-liquid interface synthesis provided a unique way to selectively and efficiently prepare molecular complexes (ML(2)) and metastable porous coordination networks in short crystallization times. In sharp contrast, their solution reactions gave interpenetrated open-framework networks. We succeeded in solving a crystal structure of the metastable network by ab initio powder X-ray analysis.
固-液界面合成为在短结晶时间内选择性和有效地制备分子配合物（ML(2)）和亚稳多孔配位网络提供了一种独特的方法。相比之下，它们的溶液反应得到了互穿的开放式骨架网络。我们通过从头粉末 X 射线分析成功解决了亚稳网络的晶体结构。
