Massachusetts Institute of Technology, Department of Materials Science and Engineering, 77 Massachusetts Avenue, Cambridge, MA 02139, USA.
Chem Commun (Camb). 2010 Sep 14;46(34):6246-8. doi: 10.1039/c0cc01829e. Epub 2010 Aug 10.
A simple and versatile approach was developed to generate hierarchical assemblies of ultra-small gold nanocluster thin films using the combination of galvanic reaction and a block copolymer coordinated with gold complex. Variation of the temperature allows effective control over the optical response of these stimuli-responsive organic-nanocluster hybrid structures.
开发了一种简单且通用的方法，通过电化学反应和与金配合物配位的嵌段共聚物的组合，生成超小金纳米团簇薄膜的分级组装体。温度的变化可以有效地控制这些刺激响应的有机-纳米团簇杂化结构的光学响应。
