• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

单分散双(酞菁基)铽在铜表面的自旋和轨道磁矩各向异性。

Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato)terbium on a copper surface.

机构信息

Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany.

出版信息

J Am Chem Soc. 2010 Sep 1;132(34):11900-1. doi: 10.1021/ja105124r.

DOI:10.1021/ja105124r
PMID:20698538
Abstract

The magnetic properties of isolated TbPc(2) molecules supported on a Cu(100) surface are investigated by X-ray magnetic circular dichroism at 8 K in magnetic fields up to 5 T. The crystal field and magnetic properties of single molecules are found to be robust upon adsorption on a metal substrate. The Tb magnetic moment has Ising-like magnetization; XMCD spectra combined with multiplet calculations show that the saturation orbital and spin magnetic moment values reach 3 and 6 mu(B), respectively.

摘要

采用 X 射线磁圆二色性技术，在 8 K 温度和高达 5 T 的磁场下，研究了孤立的 TbPc(2)分子在 Cu(100)表面上的磁性。研究发现，在金属衬底上吸附后，单个分子的晶体场和磁性仍然保持稳定。Tb 磁矩具有类 Ising 磁化特性；X 射线磁圆二色光谱与多体计算相结合表明，饱和轨道和自旋磁矩值分别达到 3 和 6 μB。

相似文献

1
Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato)terbium on a copper surface.单分散双(酞菁基)铽在铜表面的自旋和轨道磁矩各向异性。
J Am Chem Soc. 2010 Sep 1;132(34):11900-1. doi: 10.1021/ja105124r.
2
A star-shaped heteronuclear Cr(III)Mn(II)3 species and its precise electronic and magnetic structure: spin frustration studied by X-ray spectroscopic, magnetic, and theoretical methods.一种星状异核 Cr(III)Mn(II)3 物种及其精确的电子和磁结构：通过 X 射线光谱、磁性和理论方法研究的自旋阻挫。
Inorg Chem. 2010 Mar 1;49(5):2093-102. doi: 10.1021/ic9012119.
3
X-ray magnetic circular dichroism of Pseudomonas aeruginosa nickel(II) azurin.铜绿假单胞菌镍（II）型天青蛋白的X射线磁圆二色性
J Am Chem Soc. 2004 May 12;126(18):5859-66. doi: 10.1021/ja036218d.
4
Addressing the magnetic properties of sub-monolayers of single-molecule magnets by X-ray magnetic circular dichroism.通过 X 射线磁圆二色性研究单分子磁体亚单层的磁性。
Nanoscale. 2010 Dec;2(12):2698-703. doi: 10.1039/c0nr00483a. Epub 2010 Oct 12.
5
Magnetic interactions in CuII-LnIII cyclic tetranuclear complexes: is it possible to explain the occurrence of SMM behavior in CuII-TbIII and CuII-DyIII complexes?铜（II）-镧（III）环状四核配合物中的磁相互作用：能否解释铜（II）-铽（III）和铜（II）-镝（III）配合物中单分子磁体行为的出现？
Inorg Chem. 2007 May 28;46(11):4458-68. doi: 10.1021/ic062252s. Epub 2007 Apr 26.
6
A novel 1,2,4-triazole-based copper(II) complex: synthesis, characterization, magnetic property and nuclease activity.一种新型 1,2,4-三唑铜(II)配合物的合成、表征、磁性和核酸酶活性。
J Inorg Biochem. 2010 Feb;104(2):171-9. doi: 10.1016/j.jinorgbio.2009.10.020. Epub 2009 Oct 29.
7
Ligand effects on the structures and magnetic properties of tricyanomethanide-containing copper(II) complexes.配体对含三氰基甲烷铜（II）配合物结构和磁性的影响。
Dalton Trans. 2007 Nov 28(44):5190-200. doi: 10.1039/b709233d. Epub 2007 Sep 6.
8
Crystal structures and magnetic properties of complexes of M(II)Cl2 (M = Cu, Ni, and Co) coordinated with 4-(N-tert-butyloxyamino)-2-(methoxymethylenyl)pyridine: 2D magnetic anisotropy of the aminoxyl-Co(II) complex in the crystalline state.M(II)Cl₂（M = 铜、镍和钴）与4-(N-叔丁氧基氨基)-2-(甲氧基亚甲基)吡啶配位的配合物的晶体结构和磁性：晶体状态下氨基氧自由基-钴(II)配合物的二维磁各向异性
Inorg Chem. 2005 Aug 22;44(17):6004-11. doi: 10.1021/ic048441x.
9
Covalent linkage of the type-2 and type-3 structural mimics to model the active site structure of multicopper oxidases: synthesis and magneto- structural properties of two angular trinuclear copper(II) complexes.通过2型和3型结构模拟物的共价连接来模拟多铜氧化酶的活性位点结构：两种角形三核铜（II）配合物的合成及磁结构性质
Inorg Chem. 2003 Sep 8;42(18):5660-8. doi: 10.1021/ic034565i.
10
Probing the magnetic properties of three interconvertible redox states of a single-molecule magnet with magnetic circular dichroism spectroscopy.用磁圆二色光谱研究单个分子磁体三种可转换氧化还原态的磁性。
J Am Chem Soc. 2010 Feb 17;132(6):1756-7. doi: 10.1021/ja9095895.

引用本文的文献

1
Orientation-Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide-Based Single-Ion Magnets Adsorbed on Ag(100).吸附在Ag(100)上的基于环辛四烯铒(III)的单离子磁体的取向驱动大磁滞
Small Sci. 2024 Apr 24;4(8):2400115. doi: 10.1002/smsc.202400115. eCollection 2024 Aug.
2
Nanomaterial-based sensors for microbe detection: a review.用于微生物检测的纳米材料基传感器：综述
Discov Nano. 2024 Jul 30;19(1):120. doi: 10.1186/s11671-024-04065-x.
3
Synthesis and Dynamic Behavior of Ce(IV) Double-Decker Complexes of Sterically Hindered Phthalocyanines.
位阻酞菁铈（IV）双层配合物的合成与动态行为
Molecules. 2024 Feb 17;29(4):888. doi: 10.3390/molecules29040888.
4
Adsorption of lanthanide double-decker phthalocyanines on single-walled carbon nanotubes: structural changes and electronic properties as studied by density functional theory.镧系双酞菁在单壁碳纳米管上的吸附：密度泛函理论研究的结构变化和电子性质。
J Mol Model. 2023 Apr 26;29(5):158. doi: 10.1007/s00894-023-05557-w.
5
Spin-orbital Yu-Shiba-Rusinov states in single Kondo molecular magnet.单近藤分子磁体中的自旋轨道汤川-芝-鲁西诺夫态
Nat Commun. 2022 Oct 27;13(1):6388. doi: 10.1038/s41467-022-34187-8.
6
Magnetic molecules as local sensors of topological hysteresis of superconductors.作为超导体拓扑磁滞局部传感器的磁性分子。
Nat Commun. 2022 Jul 4;13(1):3838. doi: 10.1038/s41467-022-31320-5.
7
Magnetic properties of on-surface synthesized single-ion molecular magnets.表面合成单离子分子磁体的磁性
RSC Adv. 2019 Oct 25;9(59):34421-34429. doi: 10.1039/c9ra06803a. eCollection 2019 Oct 23.
8
Understanding the Superior Stability of Single-Molecule Magnets on an Oxide Film.理解单分子磁体在氧化物薄膜上的卓越稳定性。
Adv Sci (Weinh). 2019 Sep 30;6(22):1901736. doi: 10.1002/advs.201901736. eCollection 2019 Nov.
9
Thermostability and photoluminescence of Dy(iii) single-molecule magnets under a magnetic field.磁场下Dy(iii)单分子磁体的热稳定性和光致发光
Chem Sci. 2016 Aug 1;7(8):5020-5031. doi: 10.1039/c6sc01157h. Epub 2016 May 12.
10
Sub-molecular modulation of a 4f driven Kondo resonance by surface-induced asymmetry.表面诱导不对称对4f驱动的近藤共振的亚分子调制。
Nat Commun. 2016 Sep 26;7:12785. doi: 10.1038/ncomms12785.