Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany.
Beilstein J Org Chem. 2010 Jul 2;6:72. doi: 10.3762/bjoc.6.72.
(Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations.
（寡）苯并噻嗪基硫代乙酸酯，通过一锅法序列合成，可电化学氧化且具有强荧光性。在金覆盖的硅片存在的情况下，通过对硫代乙酸酯的现场脱保护作用，很容易从巯基制备 SAMs。通过椭圆测量法确认单层形成，并将结果与通过力场和 DFT 计算获得的结果进行比较。
