微生物芳烃氧化中反轴系列的获取：三羰基铁(0)络合物诱导的新型二烯重排。
Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation.
机构信息
Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):215-7. doi: 10.1039/c0cc01169j. Epub 2010 Aug 20.
PMID:20730137
Abstract
A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.
摘要
微生物芳环 1,2-二羟基化作用制备的环己二烯配体在与三羰基铁(0)络合时会自发重排。随后去除铁可提供一种新的途径，得到与直接微生物芳环氧化得到的产物对映异构体的芳基 2,3-二羟基化产物。
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