芘并-sub 酞菁。
Pyrene-fused subphthalocyanine.
机构信息
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):316-8. doi: 10.1039/c0cc01877e. Epub 2010 Aug 23.
PMID:20730176
Abstract
A pyrene-fused subphthalocyanine synthesized from a reaction of 2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene and tetrafluorophthalonitrile exhibits red-shifted Q-band absorption and a unique linear arrangement in the solid state caused by a π-π stacking interaction. The concave conjugation of the SubPc moiety and the planar conjugation of the pyrene moiety enhanced its co-crystallization with C(60) molecules.
摘要
一种由 2,7-二叔丁基-4,5,9,10-四氰基芘和四氟苯甲腈反应合成的芘并-subphthalocyanine 表现出红移的 Q 带吸收和在固态中由 π-π 堆积相互作用引起的独特线性排列。SubPc 部分的凹面共轭和芘部分的平面共轭增强了其与 C(60)分子的共结晶。
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