从钯催化的氯嘧啶羟基化反应出发，设计并合成了四核簇单膦环钯化二茂铁基嘧啶酮配合物。
Design and synthesis of tetranuclear cluster monophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine.
机构信息
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022, China.
出版信息
Chem Commun (Camb). 2010 Sep 28;46(36):6852-4. doi: 10.1039/c0cc01870h. Epub 2010 Aug 23.
Hydroxylation of a monomeric triphenylphosphine-cyclopalladated ferrocenylchloropyrimidine [PdCl{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))-N(2)C(4)H(2)-Cl]}(PPh(3))] with KOH gave the first example of a tetranuclear cluster monophosphine-palladacycle Pd{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))-N(2)C(4)H(2)O]}(PPh(3)). Additionally, the analogous tricyclohexylphosphine tetranuclear cluster palladacycle has also been successfully synthesized by the same method.
单体三苯基膦环钯二茂铁基氯嘧啶[PdCl{[(η(5)-C(5)H(5))]Fe[(η(5)-C(5)H(3))-N(2)C(4)H(2)-Cl]}(PPh(3))]}与 KOH 的羟基化反应得到了四核簇单核钯环钯化合物Pd{[(η(5)-C(5)H(5))]Fe[(η(5)-C(5)H(3))-N(2)C(4)H(2)O]}(PPh(3))的第一个实例。此外，通过相同的方法还成功合成了类似的三环己基膦四核簇钯环钯化合物。
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