Department of Chemistry, Tsinghua University, Beijing 100084, PR China.
Langmuir. 2010 Sep 21;26(18):14885-8. doi: 10.1021/la102406u.
The observation of the surface of a red rose petal indicates that there are micropapillae on the surface and many nanofolders exist on each papilla. Here, much tinier nanorods with periodic pattern on the nanofolders can be seen by in situ atomic force microscopy (AFM). Angle-resolved UV-vis spectral measurement and reflectance UV-vis spectra by immersion red rose petal in solvents with different refractive indices demonstrate that such periodic nanostructures can induce structural color. The combination of structural color, driven by the nanostructures, and chemical color, driven by pigments, provide flowers bright color and special functions for human and animals' visual system. Biomimic polymer films, that fabricated by duplicating the petal's hierarchical micro/nano structures, exhibit only structural color by UV-vis spectra since there is no pigment introduced.
观察红玫瑰花瓣的表面表明,表面有微乳头状突起,每个乳头状突起上存在许多纳米褶皱。在这里,可以通过原子力显微镜(AFM)原位观察到纳米褶皱上具有周期性图案的更小的纳米棒。通过角分辨紫外可见光谱测量和将红玫瑰花瓣浸入具有不同折射率的溶剂中的反射紫外可见光谱表明,这种周期性纳米结构可以诱导结构色。由纳米结构驱动的结构色和由颜料驱动的化学色的结合,为花朵提供了对人和动物视觉系统有明亮色彩和特殊功能。通过复制花瓣的层次微/纳米结构制造的仿生聚合物薄膜,由于没有引入颜料,因此仅通过紫外可见光谱显示结构色。