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Ag2O/TiO2 纳米带异质结构,具有增强的紫外可见光光催化活性。

Ag2O/TiO2 nanobelts heterostructure with enhanced ultraviolet and visible photocatalytic activity.

机构信息

State Key Laboratory of Crystal Materials, Center of Bio & Micro/Nano Functional Materials, Shandong University, 27 Shandanan Road, Jinan 250100, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2010 Aug;2(8):2385-92. doi: 10.1021/am100394x.

Abstract

Ag(2)O/TiO(2) heterostructure with high photocatalytic activity both in ultraviolet and visible-light region was synthesized via a simple and practical coprecipitation method by using surface-modified TiO(2) nanobelts as substrate materials. The as-prepared heterostructure composite included Ag(2)O nanoparticles assembled uniformly on the rough surface of TiO(2) nanobelts. Comparing with pure TiO(2) nanobelts and Ag(2)O nanoparticles, the composite photocatalyst with a wide weight ratio between TiO(2) and Ag(2)O exhibited enhanced photocatalytic activity under ultraviolet and visible light irradiation in the decomposition of methyl orange (MO) aqueous solution. On the basis of the characterization by X-ray diffraction, photoluminescence and UV-vis diffuse reflectance spectroscopies, two mechanisms were proposed to account for the photocatalytic activity of Ag(2)O/TiO(2) nanobelts' heterostructure.

摘要

通过简单实用的共沉淀法,以表面修饰的 TiO2 纳米带为基底材料,制备出具有高光催化活性的 Ag2O/TiO2 异质结构,在紫外光和可见光区均有活性。所制备的异质结构复合材料包括均匀组装在 TiO2 纳米带粗糙表面上的 Ag2O 纳米颗粒。与纯 TiO2 纳米带和 Ag2O 纳米颗粒相比,在 TiO2 和 Ag2O 之间具有较宽的重量比的复合光催化剂在紫外光和可见光照射下,在甲基橙(MO)水溶液的分解中表现出增强的光催化活性。基于 X 射线衍射、光致发光和紫外-可见漫反射光谱的表征,提出了两种机制来解释 Ag2O/TiO2 纳米带异质结构的光催化活性。

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