采用改性脲和硫脲基受体的阴离子络合和传感。
Anion complexation and sensing using modified urea and thiourea-based receptors.
机构信息
Department of Chemistry, College of Chemistry and Chemical Engineering, and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China.
出版信息
Chem Soc Rev. 2010 Oct;39(10):3729-45. doi: 10.1039/b926160p. Epub 2010 Aug 25.
This critical review highlights recent advances in the structurally modified (thio)urea-based receptors for anion complexation and sensing. Modifications of the (thio)urea structure are aimed at a better anion binding in terms of higher binding constant, anion selectivity and feasibility. Major (thio)urea receptors are reviewed as N-alkyl, N-aryl and N-amido/N-amino (thio)ureas. Hints for designing (thio)urea-based receptors for anions are discussed (102 references).
这篇评论文章重点介绍了近年来基于结构修饰的（硫）脲受体在阴离子络合和传感方面的最新进展。（硫）脲结构的修饰旨在通过更高的结合常数、阴离子选择性和可行性来更好地结合阴离子。主要的（硫）脲受体被综述为 N-烷基、N-芳基和 N-酰胺/N-氨基（硫）脲。还讨论了设计基于（硫）脲的阴离子受体的一些建议（102 篇参考文献）。
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