螺环脒类化合物：从分子识别到双功能有机催化的桥梁。
Squaramides: bridging from molecular recognition to bifunctional organocatalysis.
机构信息
Departamento de Química Orgánica (modulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
出版信息
Chemistry. 2011 Jun 14;17(25):6890-9. doi: 10.1002/chem.201003694. Epub 2011 May 17.
PMID:21590822
Abstract
In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed.
摘要
在这篇综述中，我们将从作为分子识别研究中人工阴离子受体的酰胺基唑烷酮的起源开始介绍，一直讨论到其作为在不对称有机催化中具有强大双功能氢键催化作用的最新进展。我们还将讨论酰胺基唑烷酮功能的主要特点，并与类似的脲和硫脲进行直接比较。
Zotero 插件