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高度导电的二维铜(I)4-羟基噻吩olate 网络。

Highly conducting two-dimensional copper(I) 4-hydroxythiophenolate network.

机构信息

Institute of Molecular Functional Materials, Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR.

出版信息

Chem Commun (Camb). 2010 Oct 21;46(39):7328-30. doi: 10.1039/c0cc02348e. Epub 2010 Aug 26.

DOI:10.1039/c0cc02348e
PMID:20740247
Abstract

An unprecedented 2-D Cu-S network is constructed by self-assembly coordination between Cu(I) and 4-hydroxythiophenol and its structure was determined by using powder X-ray diffraction data. The self-assembled coordination network displays ionic behavior with a bulk electrical conductivity value of 120 S cm(-1).

摘要

一个前所未有的二维 Cu-S 网络是通过 Cu(I) 和 4-羟基噻吩之间的自组装配位构建的,并通过粉末 X 射线衍射数据确定了其结构。自组装配位网络表现出离子行为,体电导率值为 120 S cm(-1)。

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